For δ13C, currently two scales exist and are in use: VPDB (Vienna Peedee belemnite) and VPDB-LSVEC (lithium carbonate prepared by H.J. Svec), as acknowledged by experts during the 12th IAEA meeting held in Vienna, 22-26 January 2024 (Camin et al., 2025, RCM, Rapid Communications in Mass Spectrometry, 2025; 39:e10018 1 of 11 https://doi.org/10.1002/rcm.10018). δ13C values reported on the VPDB and VPDB-LSVEC scale can differ, with maximum reported differences (VPDB minus VPDB-LSVEC) of +0.3 ‰ for materials with carbon isotope delta values around –45 ‰ and negligible difference (below current analytical combined uncertainty) at carbon isotope delta values close to zero.
End users should state the values of reference materials used to normalize isotope data following the minimum requirements established by IUPAC[3] and whether they are publishing δ13C values on the VPDB scale or the VPDB-LSVEC scale. Users should ensure that in one calibration they only use values for reference materials assigned on one scale.