IAEA-417

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Producing Laboratory: MESL
Marine Sediment
 

A bulk sediment sample was collected from the Venice Lagoon, Italy. This sediment was deep-frozen, dried, ground and sieved through a 250 μm stainless steel sieve. The sediment fraction of particle size less than 250 μm was homogenized by mixing it in a rotating drum for two weeks. Then, aliquots of about 40 g were packaged into glass bottles with aluminium screw caps and sealed with Teflon tape.

Recommended values (based on dry mass)

Pesticides and PCBs

AnalyteUnitRecommended value*95% Confidence  Interval
γ HCH (Lindane)ng/g0.540.39 – 0.69
pp' DDEng/g14.012.1 - 15.9
pp' DDDng/g21.018.1 - 23.9
Trans Nonachlorng/g0.320.08 - 0.56
PCB No 28ng/g5.74.7 - 6.7
PCB No 31ng/g4.13.2 - 5.1
PCB No 44ng/g9.77.2 - 12.2
PCB No 49ng/g7.85.4 - 10.2
PCB No 52ng/g17.014.5 - 19.5
PCB No 74ng/g5.12.5 - 7.7
PCB No 87ng/g19.014.4 - 23.6
PCB No 99ng/g19.011.8 - 26.2
PCB No 101ng/g42.037.1 - 46.9
PCB No 105ng/g22.019.8 - 24.2
PCB No 110ng/g42.032.9 - 51.1
PCB No 128ng/g12.09.6 - 14.4
PCB No 138ng/g45.038.4 - 51.6
PCB No 149ng/g25.018.4 - 31.6
PCB No 156ng/g5.95.1 - 6.7
PCB No 170ng/g8.15.9 - 10.3
PCB No 174ng/g3.11.9 - 4.3
PCB No 177ng/g1.81.0 - 2.6
PCB No 183ng/g3.42.4 - 4.4
PCB No 187ng/g8.15.7 - 10.5
PCB No 194ng/g2.71.9 - 3.5
PCB No 195ng/g1.20.6 - 1.8
PCB No 206ng/g1.80.9 - 2.7
PCB No 209ng/g1.20.5 - 1.9
* Average values calculated after rejection of outliers expressed on a dry mass basis

Petroleum Hydrocarbons

AnalyteUnitRecommended value*95% Confidence interval
n - C17ng/g200120 - 280
Phenanthreneng/g39003400 - 4400
1 Methyl Phenanthreneng/g320230 - 420
Anthraceneng/g630520 - 740
Chryseneng/g36003100 - 4100
Fluoreneng/g230160 - 300
Fluorantheneng/g77006800 - 8600
Pyreneng/g60005300 - 6700
Benzo [b] Fluorantheneng/g41003100 - 5100
Benzo [k] Fluorantheneng/g20001800 - 2200
Benz [a] Anthraceneng/g32002800 - 3600
Peryleneng/g1200470 - 1900
Benzo [e] Pyreneng/g30002500 - 3500
Benzo [a] Pyreneng/g28002400 - 3200
Benzo [g,h,i] Peryleneng/g23001900 - 2700
Indeno [1,2,3-c,d] Pyreneng/g27002500 - 2900
Acenaphtheneng/g180130 - 230
Dibenzothiopheneng/g280260 - 310

* Average values calculated after rejection of outliers expressed on a dry mass basis

Information values (based on dry mass)

Please note that information values are not to be used for any assessment of analytical performance or similar; they are included to provide information about the expected mass fractions/concentration levels

Chlorinated Pesticides

AnalyteUnitInformation value*95% Confidence interval
HCBng/g1.20.9 - 1.5
pp' DDTng/g19.015.8 - 22.2
op DDDng/g11.04.8 - 17.2
Heptachlorng/g2.01.1 - 2.9
Heptachlor Epoxideng/g4.81.9 - 7.7
Aldrinng/g1.61.0 - 2.2
Dieldrinng/g2.31.2 - 3.4
Endrinng/g7.14.3 - 9.9
α Endosulfanng/g14.03.5 - 24.5
β Endosulfanng/g5.12.3 - 7.9
α Chlordaneng/g1.80.7 - 2.9
γ Chlordaneng/g1.20.7 - 1.8
Aroclor 1254ng/g410310 - 520
Aroclor 1260ng/g170110 - 230

* Average values calculated after rejection of outliers expressed on a dry mass basis

PCB Congeners

AnalyteUnitInformation value*95% Confidence interval
PCB No 8ng/g1.80.3 - 3.3
PCB No 18ng/g3.72.0 - 5.4
PCB No 22ng/g1.00.1 - 1.9
PCB No 45ng/g0.460.32 - 0.60
PCB No 66ng/g23.09.6 - 36.4
PCB No 70ng/g20.010.8 - 29.2
PCB No 95ng/g20.017.6 - 22.4
PCB No 97ng/g9.15.9 - 12.3
PCB No 118ng/g43.037.4 - 48.6
PCB No 151ng/g3.93.5 - 4.4
PCB No 153ng/g39.033.2 - 44.8
PCB No 158ng/g6.01.5 - 10.5
PCB No 180ng/g16.013.8 - 18.2
PCB No 199ng/g1.20.2 - 2.2

* Average values calculated after rejection of outliers expressed on a dry mass basis

Petroleum Hydrocarbons

AnalyteUnitInformation value*95% Confidence interval
Total Aliphaticsng/g23000115000 – 345000
Resolved Aliphaticsng/g1400010000 – 18000
Unresolved Aliphaticsng/g23000123000 – 337000
Pristaneng/g42056 - 780
n - C18ng/g230120 - 350
Phytaneng/g370190 - 550
Σ n-Alkanes [C14 - C34]ng/g95005700 - 13000
Resolved Aromaticsng/g4800032000 - 64000
Biphenylng/g42.032.1 - 51.9
Naphthaleneng/g150100 - 200
1 Methyl Naphthaleneng/g5331 - 75
2 Methyl Naphthaleneng/g8111 - 150
2 Methyl Phenanthreneng/g580210 - 950
Dibenz [a,h] Anthraceneng/g1100510 - 1700

* Average values calculated after rejection of outliers expressed on a dry mass basis

The values listed above were established on the basis of statistically valid results submitted by laboratories which had participated in one or more international interlaboratory comparisons organized by the IAEA Marine Environment Laboratory, Monaco. The details concerning the criteria for qualification as a recommended or information value may be found in the respective report (attached).